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Question

What is the hybridization state of cation part of solid PCl5?

A
sp3d2
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B
sp2
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C
sp3
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D
sp3d
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Solution

The correct option is D sp3
In solid state, PCl5 prefers to exist as oppositely charged ions like [PCl4]+PCl6 as ionic bonding enhances the crystalline nature. Also, [PCl4]+=sp3 is tetrahedral while [PCl6] is octahedral. These structures fit well into each other providing extra stability to the soild structure.
Thus, solid PCl5 exist as [PCl4]+[PCl6]
The cationic part of PCl5 is[PCl4]+.
In PCl+4, Phosphorous forms 4 σbonds.
Hence, the hybridization is sp3.

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