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Question

What is the key difference between lanthanoid contraction and actinoid contraction?


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Solution

The difference between lanthanoid contraction and actinoid contraction is as follows:

Lanthanoid contractionActinoid contraction
The atomic size or the ionic radii of tri-positive lanthanide ions decrease steadily from Cerium Ce to Lutetium Lu due to increasing nuclear charge and electrons entering the inner (n-2) f orbital. This gradual decrease in the size with an increasing atomic number is called lanthanide contraction.The atomic size or the ionic radii of tri positive actinides ions decrease steadily from Thorium Th to Lawrencium Lw due to increasing nuclear charge and electrons entering the inner (n-2) f orbital. This gradual decrease in the size with an increasing atomic number is called actinide contraction.
The size contraction is smaller in lanthanoids.The size contraction is more in actinoids.
It involves the filling of the 4f orbital.It involves the filling of the 5f orbital.

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