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Question

What is the difference between Hofmann and Curtius's Rearrangement?


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Solution

Hoffmann RearrangementCurtius Rearrangement
1. It converts primary amide to primary amine.1. It converts acyl azide to isocynate.
2. The product is primary amine.2. The product is isocyante.
3. Carbon dioxide is released as side product.3. Nitrogen gas is released as side product.

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