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Question

What is the major structure of the oxy-acid of phosphorous?


A

I

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B

II

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C

III

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D

IV

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Solution

The correct option is B

II


H3PO3 is more clearly described with the structural formula HPO(OH)2. In the solid state, HP(O)(OH)2 is tetrahedral with one shorter P=O bond of 148 pm and two longer PO(H) bonds of 154 pm.

Phosphorus acid

From the given options, the structure corresponding to the above is (II).


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