Dear Student,
The chemical formula of water is H2O and its molar mass i.e. the mass of one mole or 6.022 X 1023 molecules of water is 18g. Thus,
mass of one mole of water = 18g
mass of 4 moles of water = (18 X 4)g = 72g
Thus, the mass of 4 moles of water is 72g.
Regards