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Question

What is the maximum pH of 0.10 M solution in Mg2+ from which Mg(OH)2 will not precipitate. Given : Ksp(Mg(OH)2)=1.2×1011.

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Solution

Mg(OH)2Mg2++2(OH)
Ksp=[Hg2+][OH]2
[OH]= ksp[Mg2+]=1.2×10110.1=1.1×105M
pOH=log[OH]=log(1.1×105)=5log1.1=4.959
pH=14pOHpH=9.04
Maximum pH at which no precipitation occurs.

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