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Question

What is the minimum pH necessary to cause a precipitate of Pb(OH)2(Ksp = 1.2×105) to form in a 0.12 M PbCl2 solution?

A
12.4
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B
10.0
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C
12.0
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D
11.1
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Solution

The correct option is B 10.0

The dissociation of the above salt can be written as:

Pb(OH)2Pb+2+2OH

Therefore, the equation of Ksp=[Pb+2][OH]2

In present case, it is are given that Ksp=1.2×105 and [Pb+2]=0.12M.

NOw we can calculate [OH]=1.2x105.012=104

Therefore, pOH=log(104)=log(104)=4

pH=14pOH

pH=144=10


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