What is the net work done (is calories ) when 1 mole of monoatomic ideal gas undergoes in a process described by 1,2,3,4 in given V−T graph Use: R=2cal/moleK ln2=0.7
A
−600cal
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B
−660cal
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C
+630cal
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D
+600cal
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Solution
The correct option is A+630cal W=−nRT+lnV2V1 =−1×2×300×ln2010 =−600×ln2 =−600×(0.693−0.7) =−420cal for process 2, w=nCvlnV2V1×(600−300) w=1×3×22ln1020×(600−300) w2=300×3×0.7=2.1×300 w2=−630cal for process 3, v1=40L,v2=10L,T=600R w=−nRTlnv2v1 =−1×2×600ln4010 =+1200×2ln2=1680cal.