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Question

What is the pH of a 0.50 M aqueous NaCN solution?


[pKa of HCN is 9.22]

A
11.8
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B
12.1
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C
10.7
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D
11.5
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Solution

The correct option is D 11.5
Given that- pKa=9.22, C=0.5M
NaCN+H2ONaOH+HCN0.50.50.5

We know that,
pH=12[pKw+pKa+logC]

=12[14+9.22+log(05)]

pH=22.922=11.5

option D

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