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Question

What is the standard potential of the Tl+3/Tlelectrode?

Tl+3+2eTl+ E0=1.26 vTl++eTl E0=0.336v


A

0.53v

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B

0.728v

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C

0.106v

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D

0.118v

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Solution

The correct option is B

0.728v


T|+3+2e T|+ nFE0=2×1.26×F=2.52FT|++e T| nFE0=1×(0.336)×F=0.336FT|+3+3e T| E0=2.52F0.336FnF=21843=0.728v


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