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Question

What is the standard potential of the Tl3+/Tl electrode?
Tl3++2eTl+;E=1.26 volt
Tl++eTl;E=0.336 volt.

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Solution

Tl3++2eTl+;nFE=2×1.26×F=2.52 F
Tl++eTl;nFe=1×(0.336)×F=0.336 F
Adding
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯Tl3++3eTl;E=2.52F0.336FnF=2.1843
=0.728 volt.

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