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Question

What is the standard potential of the Tl3+/Tlelectrode?

Tl3++2eTl+ E0=1.26 VTl++eTl E0=0.336 V


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Solution

Tl3++2e Tl+ nFE0=2×1.26×F=2.52FTl++e Tl nFE0=1×(0.336)×F=0.336FTl+3+3e Tl E0=2.52F0.336FnF=21843=0.728 V

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