What is the standard reduction potential (Eo) for Fe3+→Fe? Given that: Fe2++2e−→Fe;EoFe2+/Fe=−0.47V Fe3++e−→Fe2+;EoFe3/Fe2+=+0.77V
A
−0.057V
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B
+0.30V
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C
−0.30V
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D
+0.057V
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Solution
The correct option is A−0.057V EoFe3+/Fe=1×EoFe3+/Fe2++2×EoFe2+/Fe3 Here, 1, 2 and 3 represents number of electrons that participate in respective half reactions. EoFe3+/Fe=1×0.77+2×(−0.47)3 EoFe3+/Fe=−0.057V