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Structural Isomerism

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Question

What is the total number of isomers including stereoisomers that have the formula $K_{3} [C o (C N)_{6}]$ ? (All are octahedral complexes with $C o^{3 +}$ and ambidentate ligand $C N^{-}$ )

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Solution

$C N$ , being an ambidentate ligand can bind in two possible places.

$K_{3} [C o (C N_{6})] (1)$

$K_{3} [C o (C N)_{5} (N C)] (1)$

$K_{3} [C o (C N)_{4} (N C)_{2}] (2 GI)$

$K_{3} [C o (C N)_{3} (N C)_{3}] (2 GI)$

$K_{3} [C o (C N)_{2} (N C)_{4}] (2GI$

$K_{3} [C o (C N) (N C)_{5}] (1)$

$K_{3} [C o (N C)_{6}] (1)$

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