Down a group, the atomic radius increases. Across a period, the atomic radius decreases.
Explanation;
1.Down a group
THE ATOMIC RADIUS INCREASES
∙ the number of energy levels increases by 1 as we go son a group. This makes the atom larger.
∙ An increasing number of electrons shells increases the nuclear shielding. Thus, outer e- are protected from the positive charge of the nucleus by filled inner e-shells.
∙ The nuclear charge (ie. the number of protons) does increase down a group and the nucleus become more positive. How ever, the incred nuclear shielding protects the outer e- from the increases pull.
For example, Rb has a bigger atomic radius than Na
2. Across a period.
THE ATOMIC RADIUS DECREASES
∙ From L to R, no new energy levels are added to the atom (ie. electrons are not farther away).
∙ This means that the nuclear shielding stays the same (ie. these number if filled inner e- shells stays the same from L to R).
∙ However, the nuclear charge increases. More protons are added to the nucleus, making it more positive. As such, it is able to pull the outer e- inwards. The atom becomes smaller
For example, C has a smaller atomic radius than Li.