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Question

What is the trend in Atomic Radii? Which elements have a bigger Radius?

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Solution

Down a group, the atomic radius increases. Across a period, the atomic radius decreases.
Explanation;
1.Down a group
THE ATOMIC RADIUS INCREASES
the number of energy levels increases by 1 as we go son a group. This makes the atom larger.
An increasing number of electrons shells increases the nuclear shielding. Thus, outer e- are protected from the positive charge of the nucleus by filled inner e-shells.
The nuclear charge (ie. the number of protons) does increase down a group and the nucleus become more positive. How ever, the incred nuclear shielding protects the outer e- from the increases pull.
For example, Rb has a bigger atomic radius than Na
2. Across a period.
THE ATOMIC RADIUS DECREASES
From L to R, no new energy levels are added to the atom (ie. electrons are not farther away).
This means that the nuclear shielding stays the same (ie. these number if filled inner e- shells stays the same from L to R).
However, the nuclear charge increases. More protons are added to the nucleus, making it more positive. As such, it is able to pull the outer e- inwards. The atom becomes smaller
For example, C has a smaller atomic radius than Li.

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