The correct option is C 1:1
PCl5 (g)→PCl3 (g)+Cl2 (g)
One mole of phosphorous pentachloride undergoes decomposition to form one mole of phosphorous trichloride and one mole of chlorine gas.
Thus, the molar ratio of the product gases is 1:1
Volume ratio is proportional to their molar ratio
Hence, volume ratio of the product gases is 1:1