The correct option is B 0.631 kg
Molecular weight of KCl =39+35.5=74.5 g/mol
Thus, the number of moles in 1 kg or 1000 g of KCl =100074.5=13.4228 moles.
Number of moles of K=13.4228 moles
1 mol of K2O contains 2 moles of K.
Thus, number of moles of K2O=13.42282=6.711 moles.
Molecular weight of K2O =32×2+16=94 g/mol
Thus, mass of K2O =6.711×94=630.834 g =0.631 kg.