Up to Mn, the maximum stable oxidation state corresponds to sum of s and d electrons. After Mn, there is decrease in the stability of higher oxidation states. The stable oxidation states of the transition elements with the following d electron configurations in the ground state of their atoms are as shown.
3d34s2:+53d54s1:+1,+63d54s2:+2,+73d84s2:+23d44s2:+1,+6