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Question

What percent of a sample of nitrogen must be allowed to escape if its temperature, pressure and volume are to be changed from 273oC, 3.00 atm and 1.65L to 0oC,75 atm and 0.55 L?

A
85.3%
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B
27.2%
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C
81.8%
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D
76.2%
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Solution

The correct option is B 81.8%
Moles of N2 at 273o C, 3 atm and 1.65 L
n1=3×1.650.0821×546=0.110 moles
Moles of N2 at 0o C, 75 atm, 0.55 L
n2=75×0.550.0821×546=0.928 moles
% change =0.9280.111×100=81.8%

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