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Question

What reagent is used in the Hinsberg test of amines?

A
(CH3CO)2O and pyridine
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B
C6H5SO2Cl in aq. NaOH
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C
NaNO2 in aq.H2SO4
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D
CH3 (excess) followed by AgOH
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Solution

The correct option is A C6H5SO2Cl in aq. NaOH
Benzene sulphonyl chloride is used in Hinsberg's test of amines to form sulfonamides. A primary amine forms a precipitate of N-alkyl benzene sulphonamide with Hinsberg reagent. This precipitate is soluble in alkali.

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