The angle between vector A and vector B is θθ as shown above.
The resultant is shown in red. Using the cosine rule:
R2=A2+B2−2AB(cosβ)
But the magnitude of each vector is the same,
therefore
A2=A2+A2−2(A)(A)(cosβ)
cosβ=−A2−2(A2)
β=60o
θ=180o−60o=60o