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Standard XII
Chemistry
Isomerism in Coordination Compounds
What type of ...
Question
What type of isomerism is exhibited the complex
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
?
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Solution
The given compound
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
shows ionisations isomerism due to two possible ionising groups.
The isomers are
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
⇔
[
C
o
(
N
H
3
)
5
S
O
4
]
C
l
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Similar questions
Q.
What type of isomerism is exhibited by the complex
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
?
Q.
Write the types of isomerism exhibited by the following complexes.
(i)
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
(ii)
[
C
o
(
e
n
)
3
]
3
+
(iii)
[
C
o
(
N
H
3
)
6
]
[
C
r
(
C
N
)
6
]
Q.
(a) Write the formula of the following coordination compound :
Iron(III) hexacyanoferrate(II)
(b) What type of isomerism is exhibited by the complex
[
C
o
(
N
H
3
)
5
C
l
]
S
O
4
?
(c) Write the hybridisation and number of unpaired electrons in the complex [
C
o
F
6
]
3
−
. (Atomic No. of Co = 27)
Q.
What type of isomerism is present in the pair of complexes
[
C
o
(
N
H
3
)
5
B
r
]
S
O
4
and
[
C
o
(
N
H
3
)
5
S
O
4
]
B
r
?
Q.
Write the IUPAC name of the complex
[
C
r
(
N
H
3
)
4
C
l
2
]
+
. What type of isomerism does it exhibit?
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Standard XII Chemistry
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