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Question

What type(s) of intermolecular forces exist between the following pair?

HBr and H2S

A
Dipole-dipole intermolecular forces
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B
Induced dipole interactions
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C
Hydrogen bonding
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D
None of the above
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Solution

The correct option is A Dipole-dipole intermolecular forces
To identify intermolecular forces, it is useful to classify the species being considered as (1) non-polar molecules, (2) polar molecules, and (3) ions. Keep in mind that dispersion forces exist between all species. Due to the large electronegativity difference between hydrogen and bromine/sulfur, the HBr bond and HS bond are polar. The molecular interactions, thus, are dipole-dipole interactions.

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