What volume of 0.1MNaOH will be required to neutralize 100 mL of 0.1MH3PO4 using methyl red indicator to change the colour form pink (acidic medium) to yellow (basic medium)?
A
300 mL
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B
200 mL
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C
100 mL
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D
30 mL
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Solution
The correct option is C100 mL Methyl red indicates first step ionisation of H3PO4. H3PO4⇌H⨁+H2PO⊝4 n-factor=1
Ew=Mw1 and N=M×1 NaOH≡H3PO4 N1×V1=N2×V2 0.1×1×V1=0.1×1×100 V1=100 mL