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Question

What weight of HNO3 is needed to convert 62 gm P4 to H3PO4 in the reaction?
P4+HNO3 H3 PO4+NO2+H2O

A
63gm
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B
630gm
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C
315gm
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D
126gm
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Solution

The correct option is C 630gm
The balanced chemical reaction is given as:
P4+20HNO34H3PO4+20NO2+4H2O
Molecular weight of P4=124 amu
Molecular weight of HNO3=63 amu
From the balanced chemical equation, 1 mole of P4 reacts with 20 moles of HNO4
124 gm P4 reacts with 20×63 gm HNO4
62 gm P4 will react with 63×20×62124=630 gm HNO4

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