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Question

What will be the E0 value for the given half cell reaction?
Cr2+(aq)+2eCr(s)
Given:
E0 value for the half cell reaction,
Cr3+(aq)+eCr2+(aq); E0=0.41 V
Cr3+(aq)+3eCr(s); E0=0.74 V

A
+0.33 V
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B
1.15 V
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C
0.33 V
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D
0.91 V
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Solution

The correct option is D 0.91 V
ΔG0=nFE0

Cr3+(aq)+3eCr(s)....(1); ΔG01=+3F×0.74
Cr3+(aq)+eCr2+(aq)......(2); ΔG02=+F×0.41
Reversing equation (2), we get,
Cr2+(aq)Cr3+(aq)+e.....(3); ΔG03=F×0.41

Adding equation (1) and (3), we get,
Cr2+(aq)+2eCr(s).....(4); ΔG04=2F×E0

ΔG04=ΔG01+ΔG03
2F×E0=+3F×0.74F×0.41
2×E0=3×0.74+0.41
E0=3×0.74+0.412
E0=1.812
E0=0.91 V

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