What will be the major product of A and B respectively?
A
cis- but−2−ene, cis- but−2−ene
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B
cis- but−2−ene, trans- but−2−ene
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C
trans- but−2−ene, trans- but−2−ene
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D
trans- but−2−ene, cis- but−2−ene
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Solution
The correct option is B cis- but−2−ene, trans- but−2−ene H2/Pd−BaSO4 is the Lindlar's catalyst. But−2−yne in presence of H2/Pd−BaSO4 gives cis- but−2−ene. But−2−yne in presence of Na/liq.NH3 gives trans- but−2−ene.