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Acidity of Alcohols and Phenols

What will be ...

Question

What will be the major product of the following reaction?

A

o-Bromobenzoic acid

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B

m-Bromobenzoic acid

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C

p-bromobenzoic acid

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D

All of the above

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Solution

The correct option is B m-Bromobenzoic acid
-COOH group is an electron withdrawing group which deactivates the ring. Hence it is a meta directing group. Therefore electrophile will attack at meta position. The reaction is as follows:

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