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Question

What will be the pH of a solution formed by mixing 40 mL of 0.10 M HCl with 10 mL of 0.45 M NaOH?

A
12
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B
10
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C
8
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D
6
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Solution

The correct option is D 12
Millimoles of HCl=40×0.10 M=4 mmol
Millimoles of NaOH=10×0.5=4.5 mmol
Since, NaOH is in excess,
Millimoles of [OH] in mixture =(4.54)mmol
=0.5 mmol
Concentration of OH, in mixture =0.540+10M
=0.550M=0.01M
pOH=log[OH]=log[1×102]=2
From, pH+pOH=14
pH=142=12.

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