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Question

What will be the pH of an aqueous solution of 0.1 M ammonium formate 25oC?
Given : pKa(HCOOH)=3.8 and pKb(NH4OH)=4.8

A
6
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B
6.5
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C
4.5
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D
5.5
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Solution

The correct option is B 6.5
Ammonium formate is a salt of weak acid formic acid and weak base ammonium hydroxide.
here,
C/Kh<100 so we can take 1h1
So, the expression for the pH of ammonium formate is: pH=12(pKw+pKapKb).
Substitute values in the above expression:
pH=12(14+3.84.8)pH=6.5
Option C is correct.

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