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Question

What will be the pH of an aqueous solution of 1.0 M ammonium formate?

Given: pKa=3.8 and pKb=4.8.

A
7.5
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B
3.4
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C
6.5
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D
10.2
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Solution

The correct option is C 6.5
Ammonium formate is a salt of weak acid formic acid and weak base ammonia.

The expression for the pH of ammonium formate is pH=0.5(pKw+pKapKb).

Substitute values in the above expression.
pH=0.5(14+3.84.8)=6.5

Option C is correct.

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