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Question

What will be the pressure exerted by a mixture of 3.2g of methane and 4.4g of carbon dioxide contained in a 9dm3 flask at 27oC?

A
8.314×104Pa
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B
8.314×106Pa
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C
6.314×102Pa
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D
7.314×104Pa
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Solution

The correct option is D 8.314×104Pa
Solution:


Moles of CH,
nCH= Mass of CH₄/Molar mass of CH₄ [ Molar mass of CH₄] = 12+4×1=16
=3.2/16=0.2mol
Moles of CO₂
nCO = 4.4/44=0.1mol[MolarmassofCO=12+2×16=44]
Total moles =0.2+0.1=0.3mol
pV=nRT
Pressure,P=nRT/V
0.3mol×0.0821dm³atm{ k }^{ -1 }mo{ l }^{ -1 }×300K/9dm³=0.0821atm
In terms of SI unit
Pressure,p = 0.3 mol × 8.314 Pa m³k1 mol1 × 300/ 9×10⁻³ m³
Therefore, P=8.314X 104 Pa is the answer.

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