What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in Figure Explain graphically.
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Solution
If the work is done in a single step, it implies that it is an irreversible process.
Work done during compression of a gas at a constant external pressure is given by the relation W=−PExtΔV i.e. the product of the constant external pressure and the change in volume.
Now, if we plot Pressure, P on y−axis vs. Volume V on x−axis graph for the given process, then we get the following figure:
From this graph, one can obtain to be the work done on the ideal gas enclosed in the cylinder which is equal to the area covered by P–V graph (shaded region)
i.e. Work done = shaded Area = Area of shape ABViVf=−PExt×ΔV