What will happen when dilute sulphuric acid is added to sodium sulphite?
A
Na2SO3+H2SO4→Na2SO4+SO3+H2O
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B
Na2SO3+H2SO4→Na2SO3+SO2+H2O
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C
Na2SO3+H2SO4→Na2SO4+SO2+H2O
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D
Na2SO4+H2SO4→Na2SO4+SO2+H2O
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Solution
The correct option is BNa2SO3+H2SO4→Na2SO4+SO2+H2O The reaction between dil. sulphuric acid and sodium sulphite occurs in two steps and is a double replacement reaction.
In the first step, sulphuric acid reacts with sodium sulphite to give sodium sulphate and sulphurous acid.
H2SO4+Na2SO3→Na2SO4+H2SO3
In the second step, sulphurous acid, which is highly unstable decomposes spontaneously into sulphur dioxide and water.