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Question

What will happen when dilute sulphuric acid is added to sodium sulphite?

A
Na2SO3+H2SO4Na2SO4+SO3+H2O
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B
Na2SO3+H2SO4Na2SO3+SO2+H2O
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C
Na2SO3+H2SO4Na2SO4+SO2+H2O
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D
Na2SO4+H2SO4Na2SO4+SO2+H2O
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Solution

The correct option is B Na2SO3+H2SO4Na2SO4+SO2+H2O
The reaction between dil. sulphuric acid and sodium sulphite occurs in two steps and is a double replacement reaction.

In the first step, sulphuric acid reacts with sodium sulphite to give sodium sulphate and sulphurous acid.
H2SO4+Na2SO3Na2SO4+H2SO3

In the second step, sulphurous acid, which is highly unstable decomposes spontaneously into sulphur dioxide and water.
H2SO3SO2+H2O

Thus, the overall reaction is written as:
H2SO4+Na2SO3Na2SO4+SO2+H2O

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