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Question

What would happen if
(i) Calcium oxide is used to dry hydrogen chloride.
(ii) Concentrated hydrochloric acid is kept open.
(iii) Hydrogen chloride prepared in laboratory, is passed through water, using a delivery tube.

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Solution

(i) Although calcium oxide is a very good drying agent, it cannot be used to dry HCl gas because it reacts with HCl to form calcium chloride.

CaO(s) + 2HCl(aq) → CaCl2(aq) + H2O(l)
Calcium

chloride

(ii) Hydrochloric acid is made by dissolving HCl gas in water. However, the vapour pressure of HCl gas in a solution is greater than that of the ambient pressure. Because the pressure of HCl gas at the surface of the liquid is greater than that of the atmosphere, it escapes in the gaseous state into the atmosphere, when left open. This process continues until the pressure of the acid in the bottle equals the pressure of the atmosphere.

(iii) When hydrogen chloride, which is prepared in the laboratory, is passed through water using a delivery tube, it reacts rapidly with water to form hydrochloric acid and is completely ionised.

HCl(g) + H2O(l) → H3O+(aq) + Cl(aq)


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