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Question

What would you call this conformation of butane?


A

Chair

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B

Boat

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C

Totally eclipsed

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D

Partially eclipsed

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E

Gauche

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F

Anti

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Solution

The correct option is E

Gauche


I and VII, II and VI, III and V are same.

Energy vs. Dihedral agle or angle of rotation diagram:

Mainly three conformational isomers of butane

Stability order: Staggered > Gauche (Skew) > Eclipsed.

All other infinite possibilities in between staggered and eclipsed conformations are known as skew (Gauche) form.


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