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Question

When 10 ml of H2 and 12.5 ml of Cl2 are allowed to react,the final mixture contains under the same conditions.

A
22.5 ml of HCl
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B
12.5 ml of HCl
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C
20 ml of HCl
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D
2.5 ml of Cl2 and 20 ml HCl
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Solution

The correct option is A 22.5 ml of HCl
10ml H2 and 1.25ml Cl2
and 0.45 and 0.55 millimoles of H2 and Cl2
The reaction is H2+Cl22HCl.
thus, 1 moles of H2 reacts with 1 mole of Cl2 to from two of HCl.
0.45 mililmoles of H2 will react 0.45 millmoles of Cl2 to from
0.9 millimoles of HCl
0.1 millimoles of Cl2 will remain unreacted.
So, the reaction mixture will contain 0.01 millimoles of Cl2 and 0.9 millimoles of HCl
20.16 mL of HCL and 2.24mL of Cl2
Hence,
2.5ml of Cl2 and 20ml HCl
Option (D) is correct answer

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