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Question

When 2-Bromo-3-methylbutane is treated with sodium ethoxide in ethanol, what will be the major product?

A
2-methyl but-2-ene
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B
3-methyl but-1-ene
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C
2-methyl but-1-ene
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D
2-methyl sodium-butoxide
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Solution

The correct option is B 2-methyl but-2-ene
When 2-Bromo-3-methylbutane is treated with sodium ethoxide in ethanol, two alkenes are possible. The reaction mechanism follows Saytzeff's rule, hence more substituted alkene, i.e, 2methyl2butene is formed as major product.

CH3βC|CH3HBr|CαHCH3CH3CH2ONa−−−−−−−CH3CH2OHCH3C|CH3=CHCH32methylbut2ene(major product)+CH3C|HCH3CH=CH23methylbut1ene(minor product)

Option A is correct.

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