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Question

When 2 mole of C2H6 are completely burnt, 3129 KJ of heat is liberated. Calculate the heat of formation of C2H6.Hf for CO2 & H2O are -395 KJ and -286 KJ respectively.


A

81.5 KJ

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B

-81.5 KJ

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C

83.5 KJ

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D

-83.5 KJ

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Solution

The correct option is D

-83.5 KJ


The given equation is as follows:
2C2H6 + 7O24CO2 + 6H2O; H = 3129 KJ

H=Hf(products)Hf(reactants)

H=[4×Hf(CO2)+6×Hf(H2O)][2×Hf(C2H6)+7×Hf(O2)]

-3129 = [4 × (-395) + 6(-286)] - [2 × Hf (C2H6) + 7 × H (02)]

Hf(C2H6)=83.5 KJ


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