When 20g of naphthoicacid (C11H8O2) is dissolved in 50 gof benzene ( Kf=1.72KKgmol−1), a freezing point depression of 2K is observed. The van’ t Hoff factor (i) is
A
0.5
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B
1
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C
2
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D
3
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Solution
The correct option is A 0.5 Molality=(20172)×100050=2.325m ⇒−ΔTf=2=iKf.m ⇒i=21.72×2.325=0.5