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Question

When 35mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12M chromic sulphate solution, x×105 moles of lead sulphate are precipitated out.The value of x Rounded off to the nearest integer is.

A
525.0
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B
525
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C
525.00
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Solution

3Pb(NO3)2+Cr2(SO4)33PbSO4+2Cr(NO3)3

mmol of Cr2(SO4)3=20×0.12=2.4 mmol
Pb(NO3)2=35×0.15=5.25 mmol
3 mmol Pb(NO3)2reacts with 1 mmol Cr2(SO4)3
5.25 mmol Pb(NO3)2reacts with 1.75 mmol Cr2(SO4)3
Limiting reagent is lead nitrate
So, 5.25 mmol of lead sulphate are precipitated.
Moles of PbSO4 formed=5.25×103=525×105
value of x is 525

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