When 35mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12M chromic sulphate solution, x×10−5 moles of lead sulphate are precipitated out.The value of x Rounded off to the nearest integer is.
A
525.0
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B
525
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C
525.00
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Solution
3Pb(NO3)2+Cr2(SO4)3→3PbSO4+2Cr(NO3)3
mmol ofCr2(SO4)3=20×0.12=2.4mmol Pb(NO3)2=35×0.15=5.25mmol 3mmolPb(NO3)2reacts with 1mmolCr2(SO4)3 5.25mmolPb(NO3)2reacts with 1.75mmolCr2(SO4)3
Limiting reagent is lead nitrate
So, 5.25mmol of lead sulphate are precipitated. Moles of PbSO4 formed=5.25×10−3=525×10−5
value of x is 525