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Question

When a carbohydrate reacts with NaBH4, the product is an:

A
Alditol
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B
Aldaric acid
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C
Aldonic acid
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D
Aglycone
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Solution

The correct option is A Alditol
When a carbohydrate reacts with NaBH4, the product is an alditol.
The C=O groups in open chain forms of carbohydrates can be reduced to alcohols by sodium borohydride, NaBH4, or catalytic hydrogenation (H2, Ni, EtOH/H2O). Aldehydes, i.e. aldoses, are reduced to primary alcohols. Ketones, i.e. ketoses, are reduced to secondary alcohols.

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