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Nomenclature of Coordination Compounds

When a coordi...

Question

When a coordination compound $C O C l_{3} .6 N H_{3}$ is mixed with $A g N O_{3}$ , 3 moles of AgCl are prepitated per mole of the compound. write
i) structure formula of the complex.
ii) IUPAC name of the complex.

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Solution

$C o C l_{3} .6 N H_{3} + A g N O_{3} ⟶ 3$ mole of $A g C l ↓$
Structural formula of complex= $[C o (N H_{3})_{6}] C l_{3}$
IUPAC name $⟶$ Hexaamine Cobalt (III) chloride
It is a coordination compound. $3$ moles of $A g C l$ is precipitated, so, three $C l^{⊝}$ ions are outside the coordination sphere.

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Q. When a coordination compound

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(ii) IUPAC name of the complex.

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