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Question

When a mixture of potassium cyanate and ammonium sulphate is heated, it gives:

A
urea
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B
methanamide
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C
ethanamide
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D
none
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Solution

The correct option is A urea
When a mixture of potassium cyanate and ammonium chloride is heated, it gives urea.

A solution of potassium cyanate and ammonium sulphate is evaporated to dryness when ammonium cyanate is formed, which then undergoes rearrangement to form urea.

2KCNO+(NH4)2SO42NH4CNO+K2SO4

NH4CNOrearrangement−−−−−−−−H2NCONH2

Option A is correct.

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