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Question

When a real gas expands adiabatically against a finite pressure, its

A
internal energy increases
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B
internal energy decreases
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C
temperature always increases
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D
internal energy remains constant
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Solution

The correct option is B internal energy decreases
From the first law of thermodynamics,
dU=q+W
In adibatic process no change of heat takes place.
So, dU=W
Since, the gas is expanding, the work is done by the gas.
dU=W.
Hence internal energy of the system decreases.
Again, dU=Cv(T2T1)=W
Since here W is negative, so T1>T2.
So temperature will also decrease.





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