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Question

When a solution of sodium chloride containing ethyl alcohol is electrolyzed, it forms:

A
ethyl alcohol
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B
chloral
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C
chloroform
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D
acetaldehyde
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Solution

The correct option is B chloroform
When a solution of sodium chloride containing ethyl alcohol is electrolyzed, it forms chloroform.

The electrolysis of sodium chloride gives chlorine and sodium hydroxide.

The ethyl alcohol reacts with chlorine and NaOH to give haloform reaction.
CH3CH2OH+4Cl2+6NaOHCHCl3+HCOONa+5NaCl

Option C is correct.

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