When a strong acid and a strong base are mixed, the heat released is maximum in the case of
25 ml of 0.1 M-HCl + 25 ml of 0.1 M-NaOH
Greater the mill equivalents of strong acid and strong base, higher is the heat liberated.
25 ml of 0.1M HCl=NV=.1X25=2.5milli equivalentssdf
25 ml of 0.1M NaOH=NV=.1X25=2.5milli equivalents, as both have same milli equivalents the heat liberated is more,in other options the milli equivalents are less.