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Question

When alcohol (C2H5OH) and acetic acid are mixed together in equimolar ratio at 27C, 33 % is converted into ester. Then the Kc for the equilibrium is:
C2H5OH(l)+CH2COOH(l)CH3COOC2H5(l)+H2O(l)

A
4
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B
1/4
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C
9
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D
1/9
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Solution

The correct option is B 1/4
C2H5OH(l)+CH2COOH(l)CH3COOC2H5(l)+H2O(l)

10.33 10.33 0.330.33
Kc=0.33×0.330.67×0.67=14

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