When an aqueous solution of sodium sulphate is electrolysed, on cathode we get:
H2
During electrolysis of aqueous sodium sulphate, water gets reduced at the cathode liberating hydrogen gas and oxygen gets liberated at the anode due to oxidation.
At cathode:
2H2O + 2e−→H2 + 2OH−At anode:
2H2O → O2 + 4H+ +4e−